Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in … If not breathing, give artificial respiration. Methylene chloride is incompatible with alkali metals, strong oxidizing agents, strong bases, and oxides of nitrogen, zinc, aluminum, water, magnesium, and amines. OSHA Vacated PELs: Methylene Blue: No OSHA Vacated PELs are listed for this chemical. Flammable Properties: Can ignite if strongly heated. SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Transport information DOT UN-No UN1593 Proper Shipping Name DICHLOROMETHANE Hazard Class 6.1 Packing Group III TDG Methylene chloride is an industrial solvent used in commercial paint strippers and degreasing agents. EPA has a Methylene Chloride Hazard Summary. Provides references that may aid in recognizing methylene chloride hazards in the workplace. Methylene chloride can be particularly dangerous when used in small rooms with no ventilation. Suitable Extinguishing Media: Carbon dioxide, dry chemical powder, appropriate foam, water spray or fog. Methylene Chloride: Hazards. These effects can result from inhalation or dermal exposure to methylene chloride. CDC - NIOSH Pocket Guide to Chemical Hazards - Methylene chloride Closed containers exposed to heat may explode. Handling Guidelines for Minimizing Worker Exposure Causes moderate to severe irritation. Source Products By Show Name: This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Methylene chloride - 75-09-2 U080 - 14. Potential Acute Health Effects: Very hazardous in case of eye contact (irritant), of ingestion, of inhalation. Potential cancer hazard. Hazard classification & labelling Hazard classification and labelling. Appearance: colorless liquid. This complex is called carboxyhemoglobin (COHb) and results in a reduction in the oxygen carrying capacity of the blood. Methylene chloride is on the Proposition 65 list because it can cause cancer. Methylene chloride Revision Date 28-Nov-2019 Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Inflammation of the eye is characterized by redness, watering, and itching. (1,6) The chemical formula for methylene chloride is CH 2 Cl 2, and the molecular weight is 84.93 g/mol. METHYLENE CHLORIDE _____ SDS No. Potential cancer hazard. The primary exposure route for methylene chloride is via inhalation, although absorption through the skin is also a concern. Hazard alert | Methylene chloride hazards for bathtub refinishers (OSHA/NIOSH) Methylene chloride can be particularly dangerous when used in small rooms with no ventilation. : M47008 Rev. ; Proposition 65 requires businesses to determine if they must provide a warning about exposures to listed chemicals. Material Safety Data Sheet Dichloromethane MSDS Number: BDH-120 Page 1 of 9 1. It is metabolized by the body to carbon monoxide, and can affect the blood’s ability to transport oxygen. Methylene Chloride ACS Safety Data Sheet 1. Causes eye, skin, and respiratory tract irritation. Methylene chloride (OSHA) The most common means of exposure to methylene chloride is inhalation and skin exposure. Potential Hazards: Methylene chloride/dichloromethane exposure can cause central nervous system, liver, and cardiovascular effects. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. The principal hazards associated with occupational exposure to methylene chloride are the health effects it produces. Other Hazards. Methylene chloride Revision Date 28-Nov-2019 Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. METHYL CHLORIDE page 2 of 6 This Fact Sheet is a summary source of information of all potential and most severe health hazards that may result from exposure. Methylene chloride can cause serious poisoning if it is inhaled, swallowed, or spilled on the skin. Already banned in some countries, the Environmental Protection Agency (EPA) recently proposed limiting its use in the United States. The hazard alert, part of OSHA’s Fatal Facts series, states that the temporary worker was using a common paint stripper to remove bathtub coating in a small bathroom in an apartment building. Methylene chloride (CH 2 Cl 2) is a colorless liquid that can harm the eyes, skin, liver, and heart. Methylene chloride hazards for bathtub refinishers . If breathing is difficult, give oxygen. Overexposure to methylene chloride can cause both immediate and long-term health effects. This substance has caused adverse reproductive and fetal effects in animals. Methylene chloride is highly volatile with a low boiling point (104°F) and vapor pressure (350mm Hg). Warning! May cause kidney damage. Methylene chloride is metabolically converted to carbon monoxide after systemic absorption, which yields increased concentrations of carboxyhemoglobin in the blood. It’s much better than chloroform because of the following adventages: – it is less harmful – it has less penetrating odor – rinsing of gutta-percha oddments is easier If your workers use methylene chloride on the job, they may be exposed to the chemical through inhalation, absorption through the skin, or skin contact. Methylene Chloride: Hazards If your workers use methylene chloride on the job, they may be exposed to the chemical through inhalation, absorption through the skin, or skin contact. (1,4) Methylene chloride is a colorless liquid with a sweetish odor. Skin: prolonged or repeated contact may cause irritation, defatting of skin & dermatitis. [Note: A gas above 104°F.] Transport information DOT UN-No UN1593 Proper Shipping Name DICHLOROMETHANE Hazard Class 6.1 Packing Group III TDG Page 2 of 7 MSDS ± Methylene Chloride The information in CAMEO Chemicals comes from a variety of data sources. Methylene chloride is converted to carbon monoxide in the body, which reduces the oxygen carrying capacity of the ... 5.2 Special hazards arising from the substance or mixture Explosive mixtures of methylene chloride and air can be formed, but are difficult to ignite and require high intensity sources of This chemical is widely used in consumer products, yet without appropriate protections, exposure may lead to death. If skin irritation persists, call a physician. SAFETY DATA SHEET Methylene Blue According to Regulation (EC) No 1907/2006, Annex II, as amended. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Dichloromethane OTHER/GENERIC NAMES: Methylene Chloride, Methylene Dichloride, DCM, MC PRODUCT USE: Solvent MANUFACTURER: Honeywell 1953 South Harvey Street Methylene chloride (dichloromethane). It is metabolized by the body to carbon monoxide, and can affect the blood’s ability to transport oxygen. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Due to its high vapor pressure, methylene chloride can act as a simple asphyxiant by displacing air. Specifically, “In classifying the hazards of methylene chloride at least the following hazards are to be addressed: Cancer, cardiac effects (including elevation of carboxyhemoglobin), central nervous system effects, liver effects, and skin and eye irritation.” 1910.1052(k)(1)(ii) Occupational Safety & Health Administration, Occupational Safety and Health Administration, Criteria for a Recommended Standard: Occupational Exposure to Methylene Chloride, International Agency for Research on Cancer (IARC) Monographs on the Evaluation of Carcinogenic Risks for Humans, Toxicological Profile for Methylene Chloride, International Chemical Safety Cards (ICSC), Severe Storm and Flood Recovery Assistance. Methylene chloride is removed from the body mainly in expired air and urine. Specifically, “In classifying the hazards of methylene chloride at least the following hazards are to be addressed: Cancer, cardiac effects (including elevation of carboxyhemoglobin), central nervous system effects, liver effects, and skin and eye irritation.” 1910.1052 (k) (1) (ii) In the body, methylene chloride is converted to carbon monoxide. Methylene chloride is used in endodontics as a very efficient dissolving agent of gutta-percha and endomethasone. Use oxygen as required, provided a qualified operator is present. The ‘Hazard classification and labelling’ section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. In four human subjects exposed to methylene chloride (350 mg/cu m) for 2 hr, an average of 22.6 microg methylene chloride was excreted in the urine within 24 hr after the exposure. Methylene chloride may cause cancer in humans. A common synonym for methylene chloride is dichloromethane. Exposure to methylene chloride may result in interference with the delivery of oxygen to tissues and central nervous system impairment depending upon its concentration in air. Methylene chloride is a poison and may be fatal if swallowed. 75 -09 -2 Methylene chloride >99.5 200 -838-9 Hazard Symbols: XN Risk Phrases: 40 Section 3 - Hazards Identification EMERGENCY OVERVIEW Limited evidence of a carcinogenic effect. SAFETY DATA SHEET Methylene Chloride (298, 299, 300) 000000011394 Version 1.3 3 Revision Date 10/04/2017 Print Date 11/16/2017 3/13 4. Because methylene chloride is a volatile liquid, exposure can occur through inhalation. Provides references that may aid in evaluating methylene chloride exposures in the workplace. C). Causes eye, skin, and respiratory tract irritation. Pennsylvania RTK : Methylene chloride Massachusetts RTK : Methylene chloride TSCA 8(b) Inventory : Methylene chloride SARA 313 toxic chemical notification and release reporting : Methylene chloride CERCLA : Hazardous Substances : Methylene chloride Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Methylene chloride is an industrial solvent used in commercial paint strippers and degreasing agents. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in … Exposure can cause drowsiness, dizziness, numbness and tingling limbs, and nausea. Already banned in some countries, the Environmental Protection Agency (EPA) recently proposed limiting its use in the United States. In seven subjects exposed to 710 mg/cu m for 2 hr, the corresponding value was 81.5 ug. Inhalation Remove to fresh air. Methylene chloride poisoning incidents during paint stripping operations and bath tub refinishing have demonstrated that inhalation exposure at extremely high levels can be fatal to humans. The primary routes of exposure to methylene chloride are by inhalation and direct contact with the skin and eyes. Exposures to methylene chloride are addressed in specific OSHA standards for general industry, maritime, and construction. Combined with its heavier-than-air molecular weight (85), methylene chloride is a serious inhalation hazard. It is a suspected carcinogen. Methylene chloride Revision Date 28-November-2019 Component RCRA - U Series Wastes RCRA - P Series Wastes Methylene chloride - 75-09-2 U080 - 14. May be harmful if inhaled. Methylene chloride Revision Date 28-November-2019 Component RCRA - U Series Wastes RCRA - P Series Wastes Methylene chloride - 75-09-2 U080 - 14. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders, eye problems, impaired liver, kidney, respiratory or cardiovascular function may be more susceptible to the effects of this substance. (1,4) Methylene chloride is a colorless liquid with a sweetish odor. Employees exposed to methylene chloride are at increased risk of developing cancer, adverse effects on the heart, central nervous system and liver, and skin or eye irritation. What are the hazards associated with methylene chloride? It is a suspected carcinogen. Target Organs: Blood, central ne… Occupational Safety & Health Administration, Occupational Safety and Health Administration, Lethal Exposure to Methylene Chloride during Bathtub Refinishing, Preventing Worker Deaths from Paint Strippers Containing Methylene Chloride, Methylene Chloride Hazards for Bathtub Refinisher, Review of OSHA's Methylene Chloride standard shows value to worker protection, Notice of Availability of the Regulatory Flexibility Act Review of the Methylene Chloride Standard, Severe Storm and Flood Recovery Assistance. If you breathe methylene chloride at concentrations of 300 parts per million (ppm) or greater for a short period of time (3-4 hours) you may not be able to hear faint sounds and your vision may be slightly impaired. Washington – OSHA is warning workers of the dangers of methylene chloride after a temporary worker died from exposure to the chemical. Exposure may occur through inhalation, by absorption through the skin, or through contact with the skin. Harmful if swallowed. F (20 deg. Harmful if swallowed. Methylene chloride. Overexposure to methylene chloride can cause both immediate and long-term health effects. Methylene Chloride Hazards for Bathtub Refinishers An overview of the effects of methylene chloride in bathtub stripping products. May cause central nervous system effects. Hazard classification & labelling Hazard classification and labelling. Can harm the blood (decreased ability to carry oxygen). Dichloromethane (Methylene Chloride) Hazards & Safety Information Feb 20, 2015 Dichloromethane (also commonly known as Methylene Chloride, Methylene Dichloride, Di-clo and DCM) is a clear, slightly sweet smelling organic liquid chemical solvent which can be pose significant workplace safety risks if strict handling instructions are not followed. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders, eye problems, impaired liver, kidney, respiratory or cardiovascular function may be more susceptible to the effects of this substance. Name: Methylene Chloride Synonyms: dichloromethane; methylene dichloride; methylene bichloride CAS# 75-09-2 Product Uses: Uses Advised Against: Cleaning solvent, paint stripper, refrigeration heat transfer fluid. Booklet | Methylene chloride (OSHA) [PDF] A booklet including standards, … OSHA considers methylene chloride to be a potential occupational carcinogen. The video was produced by the California Fatality Assessment and Control Evaluation (FACE) within the Occupational Health Branch of … Methylene chloride is used in various industrial processes, in many different industries including paint stripping, pharmaceutical manufacturing, paint remover manufacturing, and metal cleaning and degreasing. Potential Hazards: Methylene chloride/dichloromethane exposure can cause central nervous system, liver, and cardiovascular effects. methylene chloride msds, US $ 480 - 580 / Metric Ton, CHLORIDE, Methylene Chloride, Methylene Chloride, 75-09-2.Source from Zhengzhou Sino Chemical Co., Ltd. on Alibaba.com. The hazard alert, part of OSHA’s Fatal Facts series, states that the temporary worker was using a common paint stripper to remove bathtub coating in a small bathroom in an apartment building. What are fire hazards and extinguishing media for methylene chloride? Dichloromethane, Methylene dichloride Colorless liquid with a chloroform-like odor. It may cause cancer. If not breathing, give artificial respiration. Washington – OSHA is warning workers of the dangers of methylene chloride after a temporary worker died from exposure to the chemical. Oxygen carrying capacity methylene chloride hazards the company/undertaking 1.1 RCRA - P Series Wastes -... 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